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Since I have started accounting for the total weight of water and meat like Dave suggests, I have had no problem with my brines. I really recommend it.
Brown sugar has impurities in it... That could have contributed to the mold....
About the amount of cure... Cure #1 is recommended to be used at a rate of 1 tsp. per 5#'s of stuff... that will give you approx. 150 ish Ppm nitrite in the final product..... 2 gallons of water + salt, sugar etc. weigh about 10 #'s per gallon... 4 small hams at ? 5#'s ? each add another 20#'s... so you have 40#'s of stuff.. that calls for 8 tsp. of cure #1 in the 40#'s of stuff.. FWIW....