I got this outta Wikipedia... Don't see where any chems are used, unless you mean created within the wood itself by the very act of a higher temp evaporation process?
I have used furniture/flooring grade wood for several years, and have not noticed a difference with seasoned "Sticks" in flavor. Now I HAVE noticed the kiln dried stuff generally burns a bit faster, and hotter, due to reduced moisture content.
A variety of wood drying kiln technologies exist today: conventional, dehumidification, solar, vacuum and radio frequency.
Conventional wood dry kilns are either package-type (sideloader) or track-type (tram) construction. Most hardwood lumber kilns are sideloader kilns in which fork trucks are used to load lumber packages into the kiln. Most softwood lumber kilns are track types in which lumber packages are loaded on kiln/track cars for loading the kiln. Of the two types the track type is far superior in lumber drying quality control (temperature and air flow rate through the lumber packages) when drying large amounts of lumber. Small lumber drying plants typically use the package (sideloader) lumber kiln.
Modern high-temperature, high-air-velocity conventional kilns can typically dry 1 inch thick green lumber in 10 hours down to a moisture content of 18%. However, 1 inch thick green Red Oak requires about 28 days to dry down to a moisture content of 8%.
Heat is typically introduced via steam running through fin/tube heat exchangers controlled by on/off pneumatic valves. Less common are proportional pneumatic valves or even various electrical actuators. Humidity is removed via a system of vents, the specific layout of which are usually particular to a given manufacturer. In general, cool dry air is introduced at one end of the kiln while warm moist air is expelled at the other. Hardwood conventional kilns also require the introduction of humidity via either steam spray or cold water misting systems to keep the relative humidity inside the kiln from dropping too low during the drying cycle. Fan directions are typically reversed periodically to ensure even drying of larger kiln charges.
Most softwood lumber kilns operate below 240 °F temperature. Hardwood lumber kiln drying schedules typically keep the dry bulb temperature below 180 °F. Difficult-to-dry species might not exceed 140 degrees F.
Dehumidification kilns are very similar to conventional kilns in basic construction. Drying times are usually comparable. Heat is primarily supplied by an integral dehumidification unit which also serves to remove humidity. Auxiliary heat is often provided early in the schedule where the heat required may exceed the heat generated by the DH unit.
Solar kilns are conventional kilns, typically built by hobbyists to keep initial investment costs low. Heat is provided via solar radiation, while internal air circulation is typically passive.
Newer wood drying technologies have included the use of reduced atmospheric pressure to attempt to speed up the drying process. A variety of vacuum technologies exist, varying primarily in the method heat is introduced into the wood charge. Hot water platten vacuum kilns use aluminum heating plates with the water circulating within as the heat source, and typically operate at significantly reduced absolute pressure. Discontinuous and SSV (super-heated steam) use atmosphere to introduce heat into the kiln charge. Discontinuous technology allows the entire kiln charge to come up to full atmospheric pressure, the air in the chamber is then heated, and finally vacuum is pulled. SSV run at partial atmospheres (typically around 1/3 of full atmospheric pressure) in a hybrid of vacuum and conventional kiln technology (SSV kilns are significantly more popular in Europe where the locally harvested wood is easier to dry versus species found in North America). RF/V (radio frequency + vacuum) kilns use microwave radiation to heat the kiln charge, and typically have the highest operating cost due to the heat of vaporization being provided by electricity rather than local fossil fuel or waste wood sources.
Valid economic studies of different wood drying technologies are based on the total energy, capital, insurance/risk, environmental impacts, labor, maintenance, and product degrade costs for the task of removing water from the wood fiber. These costs (which can be a significant part of the entire plant costs)involve the differential impact of the presence of drying equipment in a specific plant. An example of this is that every piece of equipment (in a lumber manufacturing plant) from the green trimmer to the infeed system at the planer mill is the "drying system". Since thousands of different types of wood products manufacturing plants exist around the globe, and may be integrated (lumber, plywood, paper, etc.) or stand alone (lumber only), the true costs of the drying system can only be determined when comparing the total plant costs and risks with and without drying.
The total (harmful) air emissions produced by wood kilns, including their heat source, can be significant. Typically, the higher the temperature the kiln operates at, the larger amount of emissions are produced (per pound of water removed). This is especially true in the drying of thin veneers and high-temperature drying of softwoods.